Life cycle assessment to tackle the take-make-waste paradigm in the textiles production.

Under the environmental perspective, textiles represent the fourth highest pressure commodity worldwide. In Europe, it is estimated that over 95 Mt of textile waste are generated along the entire supply chain, with still high percentages of textiles addressed to landfill or incineration. The present research, through a systematic literature review on textiles production and consumption, investigates their environmental concerns assessed through the application of the life cycle assessment. Considering the importance of identifying the products' life cycle hotspots on which actions are needed to reduce the overall impact, the manuscript focuses on the environmental performance related to the cradle-to-grave phases of textile products differentiated by type, composition, and intended use. It results that the production and use phases are those responsible for the greatest share of negative impacts, while the end-of-life generally has a small contribution. Distribution and consumption phases are less investigated, and considering the emerging consumption patterns (e.g., sharing and renting platforms), it seems essential to collect data. Circular practices can bring benefits under the environmental perspective, but in-depth studies are still required to estimate the shift of impacts from one phase of the life cycle to another. Overall, there is a paucity of studies comparing the use of different fibers, ownership models, manufacturing and disposal processes for the same functional unit, or data that would be necessary for low-impact design. The topic is still under-researched among academics and practitioners of the textile industry.

Molecular Characterization of Estrogen Receptor Agonists during Sewage Treatment Processes Using Effect-Directed Analysis Combined with High-Resolution Full-Scan Screening.

Endocrine-disrupting potential was evaluated during the sewage treatment process using in vitro bioassays. Aryl hydrocarbon receptor (AhR)-, androgen receptor (AR)-, glucocorticoid receptor (GR)-, and estrogen receptor (ER)-mediated activities were assessed over five steps of the treatment process. Bioassays of organic extracts showed that AhR, AR, and GR potencies tended to decrease through the sewage treatment process, whereas ER potencies did not significantly decrease. Bioassays on reverse-phase high-performance liquid chromatography fractions showed that F5 (log KOW 2.5-3.0) had great ER potencies. Full-scan screening of these fractions detected two novel ER agonists, arenobufagin and loratadine, which are used pharmaceuticals. These compounds accounted for 3.3-25% of the total ER potencies and 4% of the ER potencies in the final effluent. The well-known ER agonists, estrone and 17ß-estradiol, accounted for 60 and 17% of the ER potencies in F5 of the influent and primary treatment, respectively. Fourier transform ion cyclotron resonance mass spectrometry analysis showed that various molecules were generated during the treatment process, especially CHO and CHOS (C: carbon, H: hydrogen, O: oxygen, and S: sulfur). This study documented that widely used pharmaceuticals are introduced into the aquatic environments without being removed during the sewage treatment process.

Design and Operation of Effective Landfills with Minimal Effects on the Environment and Human Health.

Totaling at 7.4 billion people, the world's population is rapidly growing, bringing along with it an increase in waste generation. The impact of this exponential increase in waste generation has resulted in the increased formation and utilization of landfills. In the present day, landfills are utilized to dispose of chemical, hazardous, municipal, and electronic wastes. However, despite their convenience, most landfills are improperly managed and face constant changes from the surrounding environment that interfere with their internal landfill processes. The objectives of this mixed review are to highlight the negative impacts landfills have on the environment and public health as well as outline the need for proper management practices to mitigate these effects. Inadequate management of landfills leads to issues concerning leachate collection and landfill gas (LFG) generation, which give rise to groundwater contamination and air pollution. This paper recognizes the disadvantages of utilizing landfills as the main disposal method by focusing on these two primary effects that improper management of landfills has on the environment and human health. Many experts have also reported that communities within close proximity to improperly managed landfills have an increased risk of health issues. Apart from implementing proper landfill management practices, it is important to develop solutions to reduce waste generation altogether. This review discusses some of the innovative methods implemented by other countries to reduce landfill waste and the production of greenhouse gases as well as possible steps individuals can take to minimize their ecological footprints.

Use of Routine Environmental Monitoring Data to Establish a Dose-based Compliance System for a Low-level Radioactive Waste Disposal Site.

A dose-based compliance methodology was developed for Waste Control Specialists, LLC, low-level radioactive waste facility in Andrews, Texas, that allows routine environmental measurement data to be evaluated not only at the end of a year to determine regulatory compliance, but also throughout the year as new data become available, providing a continuous assessment of the facility. The first step in the methodology is a screening step to determine the potential presence of site emissions in the environment, and screening levels are established for each environmental media sampled. The screening accounts for spatial variations observed in background for soil and temporal fluctuations observed in background for air. For groundwater, the natural activity concentrations in groundwater wells at the facility are highly variable, and therefore the methodology uses ratios for screening levels. The methodology compares the ratio of gross alpha to U + U to identify potentially abnormal alpha activity and the ratio of U to U to identify the potential presence of depleted uranium. Compliance evaluation is conducted for any samples that fail the screening step. Compliance evaluation uses the radionuclide-specific measurements to first determine (1) if the dose exceeds the background dose and if so, (2) the dose consequences, so that the appropriate investigation or action occurs. The compliance evaluation is applied to all environmental samples throughout the year and on an annual basis to determine regulatory compliance. The methodology is implemented in a cloud-based software application that is also made accessible to the regulator. The benefits of the methodology over the existing system are presented.

Microplastics in the wastewater treatment plants (WWTPs): Occurrence and removal.

WWTPs may be one of the important ways for MPs to enter surface water. In the present study, the influent and effluent from eleven WWTPs in Changzhou were collected and analyzed. At the same time, the abundance, size, color, and shape of MPs in influent and effluent were investigated. The average abundance of MPs in the influent and effluent were 196.00 ±â€¯11.89 n/L and 9.04 ±â€¯1.12 n/L respectively, and the MPs removal efficiency of eleven WWTPs was almost over 90% in which it could be up to 97.15%. MPs were divided into four particle size based on abundance changes, and the size of MPs with the highest abundant was mainly concentrated at 0.1-0.5 mm. Among these MPs, fibers were the main shape in wastewater, followed by fragments, flakes, spheres and films. The colors of MPs in wastewater were various and 14 types of plastics were detected from wastewater using attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR). Moreover, Rayon and PET were the dominant polymer types in eleven WWTPs. The research results provided basic data for the research and supervision of MPs pollution in WWTPs.

Heavy Metal Accumulation in Water, Soil, and Plants of Municipal Solid Waste Landfill in Vientiane, Laos.

The municipal solid waste (MSW) landfill in Vientiane, Laos, which receives > 300 tons of waste daily, of which approximately 50% is organic matter, has caused serious environmental problems. This study was conducted to investigate the accumulated levels of heavy metals (HMs) (cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn)) in water (surface and groundwater), soil, and plants between dry and wet seasons according to the standards of the Agreement on the National Environmental Standards of Laos (ANESs), Dutch Pollutant Standards (DPSs), and the World Health Organization (WHO), respectively. Although no impact of pollution on the surface water was observed, the levels of Cr and Pb in the groundwater significantly exceeded the basics of ANESs and WHO in both seasons. The pollution caused by Cd and Cu reached the eco-toxicological risk level in the landfill soils and its vicinity. The vegetable Ipomoea aquatica, which is consumed by the nearby villagers, was seriously contaminated by Cr, Pb, Cu, and Zn, as the accumulation of these toxic metals was elevated to much greater levels as compared to the WHO standards. For the grass Pennisetum purpureum (elephant grass), the quantities of HMs in all plant parts were extreme, perhaps due to the deeper growth of its rhizome than I. aquatica. This study is the first to warn of serious HM pollution occurring in the water, soil, and plants in the MSW landfill of Vientiane, Laos, which requires urgent phytoremediation. The indication of what sources from the MSW principally cause the pollution of HMs is needed to help reduce the toxicological risks on Lao residents and the environment in Vientiane as well.

Improving leachate quality and optimizing CH4 and N2O emissions from a pre-aerated semi-aerobic bioreactor landfill using different pre-aeration strategies.

Landfill aeration efficiently accelerates municipal solid waste (MSW) stabilization. This method also impacts methane (CH4) and nitrous oxide (N2O) emissions during aeration. In this study, the effects of three pre-aeration strategies on leachate quality variations and CH4 and N2O emissions from three lab-scale pre-aerated semi-aerobic bioreactor landfills, which were filled with MSW, were investigated: low frequency and high frequency intermittent aeration (LIA and HIA) and continuous micro-aeration (CMA). Experimental results showed that these three strategies effectively reduced organic and N-based pollutants concentration in leachate. Compared with intermittent aeration (IA), CMA increased cumulative CH4 emissions (9234.3 mg) and resulted in a longer emission period (95 days). HIA generated the least cumulative CH4 emissions (4297.6 mg) and shortest emission period (65 days) due to organic matter loss during aeration. N2O emissions were present at low levels in early stages for each bioreactor, and then, increased by 1-3 orders of magnitude in the later stages due to low influent carbon-nitrogen ratio. HIA resulted in maximum cumulative N2O emissions (2884.6 mg) and experienced a longer emission period (179 days) compared to CMA (2281.6 mg; 151 days). LIA had the longest N2O emission period (209 days), but had the lowest cumulative N2O emissions (1486.3 mg). CH4 and N2O emissions mainly occurred in the early and later stages of landfill stabilization, respectively. Therefore, the study proposes an optimized pre-aeration strategy for practical landfill aeration management: early CMA may promote rapid organic matter removal and effective CH4 recovery; and late LIA may reduce N2O emissions.

A comprehensive multi-criteria decision making-based land capability assessment for municipal solid waste landfill sitting.

The municipal waste management has always been one of the most challenging environmental concerns. Today, although different strategies have been developed, sanitary disposal of municipal waste is still considered as one of the most widely used alternatives, especially in developing countries such as Iran. To investigate the land capability of Pishva, for landfill sitting, the important criteria were categorized in two groups of ecological and socioeconomic and then a multi-criteria decision-making model was used with decision-making trial and evaluation decision-making trial and evaluation (DEMATEL)-analytical network process (ANP) approach. First and foremost, the interaction of criteria was determined implementing DEMATEL. It was found that the soil depth criterion not only is the most effective but also is the most influenced one. Moreover, ANP structure was developed to weigh the criteria. In comparison to socioeconomic criteria, ecological ones play a more significant role. Afterwards, factor maps and constraints were standardized using fuzzy and Boolean logic, respectively, and all layers were combined to generate the final capability map of Pishva applying WLC method. The capability map showed that 71% of the area is not capable of landfilling, and only 5% of Pishva has a high capability. The results proved the great effectiveness of the methods proposed in this study.

Improving the monitoring of a dumping site in a dynamic environment. Example of the Octeville site (Bay of Seine, English Channel).

Dredged sediments have different physical and chemical characteristics compared with the sediments in place, which generates multiple effects on the environment. In this study, we show that the sampling strategy used to monitor the effects of dredge spoil deposition on the surrounding environment can lead to different interpretations. It appears that sediment sample replicates may or may not be necessary, depending on the studied area, the prevailing environmental forcings before sediment sampling and the combination of these two factors. The proposed modus operandi allows us to optimize both the confidence on the obtained results and the cost of the sediment studies (sampling and laboratory analyses). The results are based on the sediment fine fraction, which is considered as a key environmental component due, for example, to its strong association with the structure of benthic faunal communities as well as its role in the build-up of pollutants.

Carbon footprint associated with four disposal scenarios for urban pruning waste.

The inadequate disposal of urban pruning residues can cause significant environmental impacts. The objective of the study presented herein was to quantify the carbon footprint and analyze four disposal scenarios for the urban pruning waste of the city of Joao Pessoa (Northeast Brazil). Software SimaPro was utilized for the quantification of the carbon footprint, with the IPCC 2013 GWP 100y impact evaluation method. The end-of-life treatments considered were sanitary landfilling (with and without collection of methane), simple municipal incineration, and reutilization of wood (transformation into briquettes). The results indicated that simple disposal in sanitary landfill generated 136.34 kg CO2/t urban pruning waste collected (highest carbon footprint), sanitary landfill with methane collection emitted 113.43 kg CO2/t waste, municipal incineration generated 71.31 kg CO2/t waste, and reutilization of woody residues was the scenario with the lowest carbon footprint, with 27.82 kg CO2/t waste. This study demonstrated that reutilization of biomass, besides being environmentally viable, presents the potential to contribute to the city's environmental quality, including the possibility of being used to obtain carbon credits.

Systematic Review: Occupational illness in the waste and recycling sector.

BACKGROUND: The waste and recycling sector is a growing part of industry. Whether health surveillance is indicated and how it should be undertaken is unclear. AIMS: To undertake a review of the literature to identify hazards to health, biological effects and occupational illnesses for workers in the sector. METHODS: A systematic review of the published literature and two UK databases. RESULTS: Rates of fatal, non-fatal injuries and self-reported work-related illness were found to be higher in the waste and recycling sector than in UK industry as a whole. There was an increased prevalence of respiratory, gastro-intestinal and skin complaints in workers exposed to compost relative to controls. They may also be at increased risk of extrinsic allergic alveolitis, allergic bronchopulmonary aspergillosis, occupational asthma and abnormalities of lung function. Workers involved with the recycling of batteries and cables may be at risk of lead poisoning and exposure to other heavy metals. There were case reports of mercury poisoning from the recycling of fluorescent lights. Cases of occupational asthma have been reported in association with wood and paper recycling. The recycling of e-waste may cause exposure to heavy metals and organic pollutants, such as polybrominated diphenyl ethers, dioxins and polyaromatic hydrocarbons, which have been associated with damage to DNA and adverse neonatal outcomes. CONCLUSIONS: Ill-health and adverse biological effects have been described in waste and recycling workers, but their true prevalence has probably not been captured. Targeted health surveillance may be required to assess exposure and to identify occupational illness.

Does wastewater treatment plant upgrading with activated carbon result in an improvement of fish health?

In the present study, the efficiency of a wastewater treatment plant (WWTP) upgraded with a powdered activated carbon unit for the reduction of micropollutants and the related advantages for fish health have been analyzed by means of different biomarkers, i.e. histopathological investigations, analyses of glycogen content and stress proteins, as well as by chemical analyses in different matrices. Comparative analyses were conducted prior and subsequent to the installation of the additional purification unit. Chemical analyses revealed a significant reduction of several pharmaceuticals, including diclofenac, carbamazepine and metoprolol, in samples of effluent and surface water downstream of the WWTP after its upgrade. In addition, diminished concentrations of diclofenac and PFOS were detected in tissues of analyzed fish. Histopathological investigations of fish liver, gills, and kidney revealed improved tissue integrity in fish after improved wastewater treatment. In parallel, biochemical measurements of glycogen revealed increased energy resources in fish liver and, furthermore, hsp70 levels in livers of exposed rainbow trout and in kidneys of exposed brown trout were lower after than before the WWTP upgrade. In summary, additional treatment with powdered activated carbon led to a reduction of potentially hazardous chemicals in the effluent and the adjacent river and, consequently, to an improvement of fish health in the receiving water course.

Food contamination by PCBs and waste disposal crisis: Evidence from goat milk in Campania (Italy).

AIM: The study aims at investigating whether, and if so, to what extent the strong presence of urban and industrial waste in a territory may cause PCB contamination in goat milk produced therein. METHODS: We compared PCB concentrations in goat milk from three different locations in the Campania region (Italy). One of the three locations, together with its surrounding area, has long suffered from illegal waste disposal and burning mainly by the so-called Ecomafia. The other locations, not involved in these illegal activities, allowed us to create a control group of goats with characteristics very similar to those of main interest. RESULTS: In milk from the waste contaminated area we identified high PCB concentrations (six indicator PCBs amounted to 170 ng g-1 on lipid weight, on average), whereas there was an almost total absence of such pollutants in milk from the control group. Concentrations of the six indicator PCBs were above the current European maximum residue limit fixed by the EU. At the same time, we found a lower average value of lipid content and a negative relationship between lipid content and PCB concentrations. CONCLUSION: Evidence indicates the potential health risk for consumers living in areas involved in illegal dumping of waste.

Renewable energy and greenhouse gas emissions from the waste sectors of European Union member states: a panel data analysis.

In the last two decades, there has been a rich debate about the environmental degradation that results from exposure to solid urban waste. Growing public concern with environmental issues has led to the implementation of various strategic plans for waste management in several developed countries, especially in the European Union. In this paper, the relationships were assessed between economic growth, renewable energy extraction and greenhouse gas (GHG) emissions in the waste sector. The Environmental Kuznets Curve hypothesis was analysed for the member states of the European Union, in the presence of electricity generation, landfill and GHG emissions for the period 1995 to 2012. The results revealed that there is no inverted-U-shaped relationship between income and GHG emissions in European Union countries. The renewable fuel extracted from waste contributes to a reduction in GHG, and although the electricity produced also increases emissions somewhat, they would be far greater if the waste-based generation of renewable energy did not take place. The waste sector needs to strengthen its political, economic, institutional and social communication instruments to meet its aims for mitigating the levels of pollutants generated by European economies. To achieve the objectives of the Horizon 2020 programme, currently in force in the countries of the European Union, it will be necessary to increase the share of renewable energy in the energy mix.

On-site removal of antibiotics and antibiotic resistance genes from leachate by aged refuse bioreactor: Effects of microbial community and operational parameters.

The abuse of antibiotics has raised the prevalence of antibiotic resistance, which will pose potential risk to human health. Leachate, generated during the landfill treatment of municipal solid waste, is the important hotspot of the antibiotics and antibiotic resistance genes (ARGs), and no effective on-site treatment has been put forward for preventing ARGs dissemination. Herein, the aged refuse bioreactor was employed to remove antibiotics and ARGs from leachate, and the great removal performance was observed. For the detected antibiotics, the total removal efficiency was about 76.75%, and sulfanilamide and macrolide were removed with high efficiencies (>80%). Among the target ARGs, tetracycline and macrolide resistance genes (tetM, tetQ and ermB) were eliminated with 1.2-2.0 orders of magnitude. The occurrences of ARGs did not correlated with water quality parameters such as COD, total nitrogen, ammonia, nitrate and nitrite, but closely linked to the variations of the bacterial community structure. Redundancy analysis (RDA) indicated the significant correlations between four genera and the distribution of ARGs, which implied that these key genera (including potential pathogens) drove the ARGs removal. Furthermore, the hydraulic loading test confirmed that the aged refuse bioreactor was capable of achieving high removal efficiencies even under shock loading for the higher loading was negative for the proliferations of potential ARGs hosts. This study suggested that aged refuse bioreactor could be a promising way for antibiotics and ARGs on-site removal from leachate.

[Impact of waste landfills in the Saratov region on the sanitary condition of the soil].

Monitoring of environment in regions of the location of waste landfills includes the implementation of the control over a sanitary condition of soils. The main origins of the spread ofpollutants into soils are the solid particles from aerosol emissions from the functioning of landfills transmitted to surrounding territories. Within zones of the impact of three largest waste landfills in the Saratov region (Aleksandrovsky, Guselsky in the city of Saratov and Balakovsky in the city of Balakovo) there were taken 152 soil samples. According to results of the estimation in soil concentration of gross and motile forms of heavy metals of the first (Zn, Cd, Ni) and the second danger classes (Cu, Cr, Pb) there was performed the analysis of coefficients of danger- K0 and total coefficients ofpollution - Zc. There was executed the assessment of both a sanitary and hygienic condition of soils and degree of danger ofpollution. The most contrast areal features of the distribution of the danger coefficient - Ko in soils are characteristic for motile forms of heavy metals. For all three studied objects persistently there is stood out the dangerous and areal pollution of soils by association of Ni and Cu . The danger ofpollution of soils by gross forms of heavy metals is minimum. The coefficient of total pollution of Zc exceeds admissible level on motile forms of heavy metals only for the soils surrounding the Balakovo landfill. In zones of the impact of waste landfills there are located the processed lands with an adverse sanitary and hygienic condition of soils. In the region of the Guselsky object soils of the processed agricultural grounds are dangerously polluted by motile forms of Ni and Cu. In vicinities of the Balakovo waste landfill considerable areas of private gardening enterprises are dangerously polluted by the motile forms of Ni, Cu and Zn.

Environmental risks of radioactive discharges from a low-level radioactive waste disposal site at Dessel, Belgium.

The potential radiological impact of releases from a low-level radioactive waste (Category A waste) repository in Dessel, Belgium on the local fauna and flora was assessed under a reference scenario for gradual leaching. The potential impact situations for terrestrial and aquatic fauna and flora considered in this study were soil contamination due to irrigation with contaminated groundwater from a well at 70 m from the repository, contamination of the local wetlands receiving the highest radionuclide flux after migration through the aquifer and contamination of the local river receiving the highest radionuclide flux after migration through the aquifer. In addition, an exploratory study was carried out for biota residing in the groundwater. All impact assessments were performed using the Environmental Risk from Ionising Contaminants: Assessment and Management (ERICA) tool. For all scenarios considered, absorbed dose rates to biota were found to be well below the ERICA 10 µGy h-1 screening value. The highest dose rates were observed for the scenario where soil was irrigated with groundwater from the vicinity of the repository. For biota residing in the groundwater well, a few dose rates were slightly above the screening level but significantly below the dose rates at which the smallest effects are observed for those relevant species or groups of species. Given the conservative nature of the assessment, it can be concluded that manmade radionuclides deposited into the environment by the near surface disposal of category A waste at Dessel do not have a significant radiological impact to wildlife.

Principal factor and hierarchical cluster analyses for the performance assessment of an urban wastewater treatment plant in the Southeast of Spain.

Process performance and operation of wastewater treatment plants (WWTP) are carried out to ensure their compliance with legislative requirements imposed by European Union. Because a high amount of variables are daily measured, a coherent and structured approach of such a system is required to understand its inherent behavior and performance efficiency. In this sense, both principal factor analysis (PFA) and hierarchical cluster analysis (HCA) are multivariate techniques that have been widely applied to extract and structure information for different purposes. In this paper, both statistical tools are applied in an urban WWTP situated in the Southeast of Spain, a zone with special characteristics related to the geochemical background composition of water and an important use of fertilizers. Four main factors were extracted in association with nutrients, the ionic component, the organic load to the WWTP, and the efficiency of the whole process. HCA allowed distinguish between influent and effluent parameters, although a deeper examination resulted in a dendrogram with groupings similar to those previously reported for PFA.

[Effect of recultivated wastes of mining factories on children residing in the district of their location].

Wastes and tailing ponds of Tyrnyauz tungsten and molybdenum factory are the main sources of heavy metal incoming into environment in Kabardino-Balkarian Republic. The factory was closed more than 10 years ago and the recultivation of it's tailing ponds, where accumulated hundreds of millions tones of wastes, was completed. The aim of this investigation was an assessment of their possible influence on children residing in the vicinity of these tailing ponds (village Bylym). Village Verhny Baksan located about 30 km upstream of the valley of the Baksan River was chosen as reference (pure) locality. As a results of the performed investigations we revealed that in drinking water of Bylym and Verhny Baksan concentrations of molybdenum were 2.10±0.42 pg/l and 0.31±0.15 pg/l correspondingly, which is remarkably lower than maximum permitted concentrations. The concentrations of Mo, Cu and Pb in children's hair in both villages were practically the same, which indicates to the absence of their accumulation in human organism. But the quantity of cells with cytogenetic disorders in buccal epithelial cells in children from Bylym was 4.1 times higher in comparison with the corresponding index of uncontaminated area. The obtained data demonstrate that genotoxic effect of remedied tailing ponds retains.

Nuclear Waste Facing the Test of Time: The Case of the French Deep Geological Repository Project.

The purpose of this article is to consider the socio-anthropological issues raised by the deep geological repository project for high-level, long-lived nuclear waste. It is based on fieldwork at a candidate site for a deep storage project in eastern France, where an underground laboratory has been studying the feasibility of the project since 1999. A project of this nature, based on the possibility of very long containment (hundreds of thousands of years, if not longer), involves a singular form of time. By linking project performance to geology's very long timescale, the project attempts "jump" in time, focusing on a far distant future, without understanding it in terms of generations. But these future generations remain measurements of time on the surface, where the issue of remembering or forgetting the repository comes to the fore. The nuclear waste geological storage project raises questions that neither politicians nor scientists, nor civil society, have ever confronted before. This project attempts to address a problem that exists on a very long timescale, which involves our responsibility toward generations in the far future.